A glow discharge ion source with fourier transform ion cyclotron resonance mass spectrometric detection
نویسندگان
چکیده
منابع مشابه
A glow discharge ion source with fourier transform ion cyclotron resonance mass spectrometric detection.
A glow discharge (CD) ion source has been coupled to a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer using a four-element electrostatic lens to accelerate and focus ions generated external to the instrument's high magnetic field into its analyzer cell. Like other CD mass spectrometers, GD-FT-ICR can provide a quantitative measure of bulk analyte concentration with good pr...
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This review offers an introduction to the principles and generic applications of FT-ICR mass spectrometry, directed to readers with no prior experience with the technique. We are able to explain the fundamental FT-ICR phenomena from a simplified theoretical treatment of ion behavior in idealized magnetic and electric fields. The effects of trapping voltage, trap size and shape, and other nonide...
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Mass spectrometry imaging (MSI) is a powerful tool in metabolomics and proteomics for the spatial localization and identification of pharmaceuticals, metabolites, lipids, peptides and proteins in biological tissues. However, sample preparation remains a crucial variable in obtaining the most accurate distributions. Common washing steps used to remove salts, and solvent-based matrix application,...
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Fourier transform ion cyclotron resonance mass spectrometry is based on image current detection of coherently excited ion cyclotron motion. The detected signal magnitude and peak shape may be understood from idealized behavior: single ion, zero-pressure, spatially uniform magnetic field, three-dimensional axial quadrupolar electrostatic trapping potential, and spatially uniform resonant alterna...
متن کاملProbing trapped ion energies via ion-molecule reaction kinetics: Fourier transform ion cyclotron resonance mass spectrometry.
The kinetic energy-dependent Ar(+)+ N2 ion-molecule reaction has been used as a chemical "thermometer" to determine the kinetic energy of ions produced by electron ionization and trapped by using a Fourier transform ion cyclotron resonance (FTICR) mass spectrometer. The rate constant for this reaction obtained on the FTICR mass spectrometer was compared to previous work, which allowed a kinetic...
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ژورنال
عنوان ژورنال: Journal of the American Society for Mass Spectrometry
سال: 1992
ISSN: 1044-0305,1879-1123
DOI: 10.1016/1044-0305(92)87045-z